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Issue 44, 2014
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Oxidative stress of H2O2 on N,N-dimethylglycine: formation of perhydrate crystals and more

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Abstract

The first example of oxidative stress of H2O2 on the α-amino acid's amino group resulting in crystallization of not only amino acid perhydrates but also of a hydroxylamine derivative is illustrated by a study of the double methylated N-derivative of glycine. The structures of N-hydroxy-N,N-dimethylglycine and N,N-dimethylglycine perhydrates as well as anhydrous N-hydroxy-N,N-dimethylglycine were analyzed by X-ray crystallography.

Graphical abstract: Oxidative stress of H2O2 on N,N-dimethylglycine: formation of perhydrate crystals and more

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Article information


Submitted
06 Sep 2014
Accepted
16 Sep 2014
First published
16 Sep 2014

CrystEngComm, 2014,16, 10165-10168
Article type
Communication

Oxidative stress of H2O2 on N,N-dimethylglycine: formation of perhydrate crystals and more

E. A. Kapustin, V. S. Minkov and E. V. Boldyreva, CrystEngComm, 2014, 16, 10165
DOI: 10.1039/C4CE01835D

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