Issue 45, 2014
From the journal:

CrystEngComm

Ag(i)-mediated formation of a 2D cyano-bridged multinuclear silver(i) alkynyl network coupled with the C–C bond cleavage of acetonitrile†

Kun Zhou,a   Chao Qin,a   Xin-Long Wang,*a   Li-Kai Yan,a   Kui-Zhan Shaoa  and  Zhong-Min Su*a  

* Corresponding authors

a Institute of Functional Material Chemistry, Key Lab of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, Jilin, China
E-mail: wangxl824@nenu.edu.cn, zmsu@nenu.edu.cn
Fax: (+86) 431 85684009
Tel: (+86) 431 85099108

Abstract

An intriguing 2D cyano-bridged multinuclear silver(I) alkynyl network [Ag15(C[triple bond, length as m-dash]CtBu)10(CF3COO)2(CN)3]n (1) is obtained by self-assembly. The existence of CN− in 1 is assumed to have originated from the Ag(I)-mediated C–C cleavage reaction of acetonitrile under mild solvothermal conditions. Furthermore, the photoluminescence property of 1 is investigated.

Graphical abstract: Ag(i)-mediated formation of a 2D cyano-bridged multinuclear silver(i) alkynyl network coupled with the C–C bond cleavage of acetonitrile

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Article information

DOI
https://doi.org/10.1039/C4CE01707B
Article type
Communication
Submitted
19 Aug 2014
Accepted
27 Sep 2014
First published
30 Sep 2014

CrystEngComm, 2014,16, 10376-10379

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Ag(I)-mediated formation of a 2D cyano-bridged multinuclear silver(I) alkynyl network coupled with the C–C bond cleavage of acetonitrile

K. Zhou, C. Qin, X. Wang, L. Yan, K. Shao and Z. Su, CrystEngComm, 2014, 16, 10376 DOI: 10.1039/C4CE01707B

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