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Issue 43, 2014
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A new heterometallic multiligand 3D coordination polymer: synthesis and structure of [Pb(OH)]n[Ag(SCN)(CN)]n

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Abstract

The synthesis and structural characterization of a new coordination polymer [Pb(OH)]n[Ag(SCN)(CN)]n, formed by an anionic layer [Ag(CN)(μ3-SCN)]nn linked to the 1D cationic fragment [Pb(OH)]n through a bridging cyanide, is reported. We have obtained a rational combination of the pattern of laurionite-type structures (Pb(OH)X, with X = halogen, SCN) with the 2D hexagonal pattern of the silver thiocyanate. The title compound shows luminescent behaviour, and the analysis of the computed band structure allows us to describe the electronic transitions.

Graphical abstract: A new heterometallic multiligand 3D coordination polymer: synthesis and structure of [Pb(OH)]n[Ag(SCN)(CN)]n

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Supplementary files

Article information


Submitted
09 Jul 2014
Accepted
09 Sep 2014
First published
11 Sep 2014

CrystEngComm, 2014,16, 10040-10045
Article type
Paper
Author version available

A new heterometallic multiligand 3D coordination polymer: synthesis and structure of [Pb(OH)]n[Ag(SCN)(CN)]n

E. Diana, G. Gervasio, E. Priola and E. Bonometti, CrystEngComm, 2014, 16, 10040
DOI: 10.1039/C4CE01424C

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