Sandwich-like octacyanometalate-based cadmium assemblies with the 4,4′-dipyridyl sulfide ligand†
Abstract
The self-assembly of octacyanotungstate, cadmium ions, and 4,4′-dipyridyl sulfide ligands has isolated the first octacyanometalate-based cadmium compounds, which exhibit novel sandwich-like coordination networks. The effect of solvent and temperature on the formation of products was discussed.