Unexpected 1D self-assembly of carbonate-templated sandwich-like macrocycle-based Ag20S10 luminescent nanoclusters

Kun Zhou; Chao Qin; Xin-Long Wang; Kui-Zhan Shao; Li-Kai Yan; Zhong-Min Su

doi:10.1039/C4CE00867G

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Unexpected 1D self-assembly of carbonate-templated sandwich-like macrocycle-based Ag₂₀S₁₀ luminescent nanoclusters†

Kun Zhou,^a Chao Qin,^a Xin-Long Wang,*^a Kui-Zhan Shao,^a Li-Kai Yan^a and Zhong-Min Su*^a

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* Corresponding authors

^a Institute of Functional Material Chemistry, Key Lab of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, Jilin, China
E-mail: zmsu@nenu.edu.cn
Fax: (+86) 431 85684009
Tel: (+86) 431 85099108

Abstract

The first example of 1D self-assembly of carbonate-templated sandwich-like macrocycle-based Ag₂₀S₁₀ nanoclusters, {[(CO₃²⁻)@Ag₂₀(S^tBu)₁₀(CH₃COO)₈(DMF)₂]·2H₂O}_n (1), is reported. Compound 1 is stable both in the solid state and in solution. It exhibits potential wide gap semiconductor properties, reversible thermochromic luminescence behaviour and excellent electrochemical properties.

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Article information

DOI: https://doi.org/10.1039/C4CE00867G
Article type: Communication
Submitted: 23 Apr 2014
Accepted: 06 Jun 2014
First published: 12 Jun 2014

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CrystEngComm, 2014,16, 7860-7864

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Unexpected 1D self-assembly of carbonate-templated sandwich-like macrocycle-based Ag₂₀S₁₀ luminescent nanoclusters

K. Zhou, C. Qin, X. Wang, K. Shao, L. Yan and Z. Su, CrystEngComm, 2014, 16, 7860 DOI: 10.1039/C4CE00867G

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