Issue 36, 2014
From the journal:

CrystEngComm

DPDS–DPS in situ transformation at room temperature via a 1,2-nucleophilic addition mechanism†

Noelia De la Pinta,a   Ana B. Caballero,d   Gotzon Madariaga,a   José M. Ezpeleta,c   Antonio Rodriguez-Dieguez,d   Juan M. Salasd  and  Roberto Cortés*b  

* Corresponding authors

a Dpto. de Física de la Materia Condensada, Facultad de Ciencia y Tecnología, Universidad del País Vasco, Apdo. 644, 48080 Bilbao, Spain
E-mail: gotzon.madariaga@ehu.es
Fax: +34 9 4601 3500
Tel: +34 9 4601 5487

b Dpto. de Química Inorgánica, Facultad de Ciencia y Tecnología, Universidad del País Vasco, Apdo. 644, 48080 Bilbao, Spain
E-mail: roberto.cortes@ehu.es
Fax: +34 9 4601 3500
Tel: +34 9 4601 5150

c Dpto. de Química Inorgánica, Facultad de Farmacia, Universidad del País Vasco, Apdo. 450, 01080 Vitoria-Gasteiz, Spain
E-mail: jm.ezpeleta@ehu.es
Tel: +34 9 4501 3039

d Dpto. de Química Inorgánica, Facultad de Ciencias, Universidad de Granada, Avda. Fuentenueva s/n, 18071 Granada, Spain
E-mail: jsalas@ugr.es
Tel: +34 9 5824 8525

Abstract

A cleavage–reorganization reaction at room temperature has been detected in three metal organic coordination compounds synthesized from a DPDS [di(4-pyridyl)disulphide] ligand: Mn(NCS)2(DPS)4 (1), [Fe(NCS)2(DPS)2]·2H2O (2) and Zn(NCO)2(DPS) (3), [DPS = di(4-pyridyl)sulphide]. The in situ reorganization process is explained by a 1,2-nucleophilic addition mechanism.

Graphical abstract: DPDS–DPS in situ transformation at room temperature via a 1,2-nucleophilic addition mechanism

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Article information

DOI
https://doi.org/10.1039/C4CE00781F
Article type
Communication
Submitted
14 Apr 2014
Accepted
05 Jun 2014
First published
06 Jun 2014

CrystEngComm, 2014,16, 8322-8326

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DPDS–DPS in situ transformation at room temperature via a 1,2-nucleophilic addition mechanism

N. De la Pinta, A. B. Caballero, G. Madariaga, J. M. Ezpeleta, A. Rodriguez-Dieguez, J. M. Salas and R. Cortés, CrystEngComm, 2014, 16, 8322 DOI: 10.1039/C4CE00781F

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