Cluster-based networks: assembly of a (4,4) layer and a rare T-shaped bilayer from [MnIII2MnII4O2(RCOO)10] coordination clusters

Iurie L. Malaestean; Arkady Ellern; Jan van Leusen; Victor C. Kravtsov; Paul Kögerler; Svetlana G. Baca

doi:10.1039/C4CE00504J

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Cluster-based networks: assembly of a (4,4) layer and a rare T-shaped bilayer from [Mn^III₂Mn^II₄O₂(RCOO)₁₀] coordination clusters†

Iurie L. Malaestean,^a Arkady Ellern,^b Jan van Leusen,^a Victor C. Kravtsov,^c Paul Kögerler*^a and Svetlana G. Baca*^c

Author affiliations

* Corresponding authors

^a Institute of Inorganic Chemistry, RWTH Aachen University, Aachen, Germany
E-mail: paul.koegerler@ac.rwth-aachen.de

^b Ames Laboratory, Iowa State University, Ames, USA

^c Institute of Applied Physics, Academy of Sciences of Moldova, Chisinau, Moldova

Abstract

The assembly of charge-neutral mixed-valent coordination clusters [Mn^III₂Mn^II₄O₂(RCOO)₁₀] (R = CHMe₂, CMe₃) and rigid isonicotinamide or semi-rigid aldrithiol-4 exo-bridging ligands results in (4,4) layers and a 2D bilayer containing an unprecedented type of cluster-based ‘T-shaped’ motif.

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Article information

DOI: https://doi.org/10.1039/C4CE00504J
Article type: Communication
Submitted: 10 Mar 2014
Accepted: 05 Jun 2014
First published: 05 Jun 2014

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CrystEngComm, 2014,16, 6523-6525

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Cluster-based networks: assembly of a (4,4) layer and a rare T-shaped bilayer from [Mn^III₂Mn^II₄O₂(RCOO)₁₀] coordination clusters

I. L. Malaestean, A. Ellern, J. van Leusen, V. C. Kravtsov, P. Kögerler and S. G. Baca, CrystEngComm, 2014, 16, 6523 DOI: 10.1039/C4CE00504J

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