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Issue 91, 2014
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Probing the importance of π-stacking interactions in DNA-templated self-assembly of bisfunctionalized guanidinium compounds

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Abstract

Bisfunctionalized guanidinium compounds displaying aromatic side groups of varying size are shown to self-assemble in aqueous solution with single-stranded DNA through phosphodiester backbone recognition. Competition experiments indicate the importance of π-stacking interactions in the stabilization of these DNA-templated supramolecular self-assemblies.

Graphical abstract: Probing the importance of π-stacking interactions in DNA-templated self-assembly of bisfunctionalized guanidinium compounds

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Article information


Submitted
23 Jul 2014
Accepted
29 Sep 2014
First published
06 Oct 2014

Chem. Commun., 2014,50, 14257-14260
Article type
Communication

Probing the importance of π-stacking interactions in DNA-templated self-assembly of bisfunctionalized guanidinium compounds

D. Paolantoni, J. Rubio-Magnieto, S. Cantel, J. Martinez, P. Dumy, M. Surin and S. Ulrich, Chem. Commun., 2014, 50, 14257
DOI: 10.1039/C4CC05706F

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