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Issue 78, 2014
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Study of the interaction of water with the aqua-soluble dimeric complex [RuCp(PTA)2–μ-CN–1κC:2κ2N-RuCp(PTA)2](CF3SO3) (PTA = 1,3,5-triaza-7-phosphaadamantane) by neutron and X-ray diffraction in solution

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Abstract

The study of an aqueous solution of [RuCp(PTA)2–μ-CN–1κC:2κ2N-RuCp(PTA)2](CF3SO3) by neutron and X-ray diffraction revealed surprising details as to how the water molecules interact with the complex and affect its properties. The present communication demonstrates the applicability of sophisticated scattering techniques in combination with theoretical calculations to the study of coordination compounds in aqueous solution.

Graphical abstract: Study of the interaction of water with the aqua-soluble dimeric complex [RuCp(PTA)2–μ-CN–1κC:2κ2N-RuCp(PTA)2](CF3SO3) (PTA = 1,3,5-triaza-7-phosphaadamantane) by neutron and X-ray diffraction in solution

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Article information


Submitted
07 Jul 2014
Accepted
04 Aug 2014
First published
20 Aug 2014

Chem. Commun., 2014,50, 11587-11590
Article type
Communication
Author version available

Study of the interaction of water with the aqua-soluble dimeric complex [RuCp(PTA)2–μ-CN–1κC:2κ2N-RuCp(PTA)2](CF3SO3) (PTA = 1,3,5-triaza-7-phosphaadamantane) by neutron and X-ray diffraction in solution

M. Serrano-Ruiz, S. Imberti, L. Bernasconi, N. Jadagayeva, F. Scalambra and A. Romerosa, Chem. Commun., 2014, 50, 11587
DOI: 10.1039/C4CC05225K

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