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Issue 72, 2014
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Potential-driven molecular tiling of a charged polycyclic aromatic compound

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Abstract

Using in situ electrochemical scanning tunnelling microscopy (EC-STM), we demonstrate fully reversible tuning of molecular tiling between self-assembled structures with supramolecular motifs containing 2, 3, 4, 6 or 7 tectons. The structures can be explained by electrocompression of the cationic adlayer at the solid–liquid interface.

Graphical abstract: Potential-driven molecular tiling of a charged polycyclic aromatic compound

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Publication details

The article was received on 01 Jun 2014, accepted on 11 Jul 2014 and first published on 31 Jul 2014


Article type: Communication
DOI: 10.1039/C4CC04189E
Citation: Chem. Commun., 2014,50, 10376-10378

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    Potential-driven molecular tiling of a charged polycyclic aromatic compound

    K. Cui, O. Ivasenko, K. S. Mali, D. Wu, X. Feng, K. Müllen, S. De Feyter and S. F. L. Mertens, Chem. Commun., 2014, 50, 10376
    DOI: 10.1039/C4CC04189E

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