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Issue 54, 2014
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[{Cu(IPr)}2(μ-OH)][BF4]: synthesis and halide-free CuAAC catalysis

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The preparation under protic conditions of the first μ-hydroxo dicopper(I)–NHC complex is reported. Its application as a CuAAC catalyst was investigated, evidencing a remarkable enhancement of catalytic efficiency in the presence of 4,7-dichloro-1,10-phenanthroline and highlighting the beneficial effect of the absence of coordinating halides.

Graphical abstract: [{Cu(IPr)}2(μ-OH)][BF4]: synthesis and halide-free CuAAC catalysis

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The article was received on 05 May 2014, accepted on 12 May 2014 and first published on 12 May 2014

Article type: Communication
DOI: 10.1039/C4CC03346A
Citation: Chem. Commun., 2014,50, 7154-7156
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    [{Cu(IPr)}2(μ-OH)][BF4]: synthesis and halide-free CuAAC catalysis

    H. Ibrahim, R. Guillot, F. Cisnetti and A. Gautier, Chem. Commun., 2014, 50, 7154
    DOI: 10.1039/C4CC03346A

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