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Issue 49, 2014
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New synthetic pathways to the preparation of near-blue emitting heteroleptic Ir(iii)N6 coordinated compounds with microsecond lifetimes

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Abstract

A high yield synthetic route for the preparation of N6 coordinated heteroleptic Ir(III) complexes using bidentate polypyridyl type ligands is described. The complexes are near-blue emitters and show microsecond emission lifetimes, high emission quantum yields and have two quasi-reversible reduction processes between −1.0 and −1.3 V vs. Ag/AgCl.

Graphical abstract: New synthetic pathways to the preparation of near-blue emitting heteroleptic Ir(iii)N6 coordinated compounds with microsecond lifetimes

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Article information


Submitted
28 Mar 2014
Accepted
01 May 2014
First published
01 May 2014

Chem. Commun., 2014,50, 6461-6463
Article type
Communication
Author version available

New synthetic pathways to the preparation of near-blue emitting heteroleptic Ir(III)N6 coordinated compounds with microsecond lifetimes

S. Soman, J. C. Manton, J. L. Inglis, Y. Halpin, B. Twamley, E. Otten, W. R. Browne, L. De Cola, J. G. Vos and M. T. Pryce, Chem. Commun., 2014, 50, 6461
DOI: 10.1039/C4CC02249A

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