Issue 28, 2014

Supramolecular hydrogen-bonding assembly of silanediols with bifunctional heterocycles

Abstract

X-ray crystallography showcases the distinct self-association and hydrogen-bonding patterns of organic silanediols, R2Si(OH)2, with bifunctional heterocycles for supramolecular assembly. Diffusion-ordered spectroscopy (DOSY) studies identify the dominant hydrogen-bonding patterns and structures in solution, which correlate with solid-state patterns at high concentrations.

Graphical abstract: Supramolecular hydrogen-bonding assembly of silanediols with bifunctional heterocycles

Supplementary files

Article information

Article type
Communication
Submitted
25 Jan 2014
Accepted
19 Feb 2014
First published
19 Feb 2014

Chem. Commun., 2014,50, 3738-3740

Author version available

Supramolecular hydrogen-bonding assembly of silanediols with bifunctional heterocycles

N. T. Tran, S. O. Wilson and A. K. Franz, Chem. Commun., 2014, 50, 3738 DOI: 10.1039/C4CC00672K

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