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Issue 28, 2014
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Supramolecular hydrogen-bonding assembly of silanediols with bifunctional heterocycles

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Abstract

X-ray crystallography showcases the distinct self-association and hydrogen-bonding patterns of organic silanediols, R2Si(OH)2, with bifunctional heterocycles for supramolecular assembly. Diffusion-ordered spectroscopy (DOSY) studies identify the dominant hydrogen-bonding patterns and structures in solution, which correlate with solid-state patterns at high concentrations.

Graphical abstract: Supramolecular hydrogen-bonding assembly of silanediols with bifunctional heterocycles

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Supplementary files

Article information


Submitted
25 Jan 2014
Accepted
19 Feb 2014
First published
19 Feb 2014

Chem. Commun., 2014,50, 3738-3740
Article type
Communication
Author version available

Supramolecular hydrogen-bonding assembly of silanediols with bifunctional heterocycles

N. T. Tran, S. O. Wilson and A. K. Franz, Chem. Commun., 2014, 50, 3738
DOI: 10.1039/C4CC00672K

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