Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance work on Wednesday 27th March 2019 from 11:00 AM to 1:00 PM (GMT).

During this time our website performance may be temporarily affected. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 26, 2014
Previous Article Next Article

Springloaded porphyrin NHC hybrid rhodium(III) complexes: carbene dissociation and oxidation catalysis

Author affiliations

Abstract

Porphyrin rhodium(III) complexes accommodate one or two NHC ligands in the apical position, which leads to severe porphyrin distortion and dearomatization. The strain in the bis(carbene) complex induces facile carbene dissociation and the formation of a catalytically active site for alcohol oxidation.

Graphical abstract: Springloaded porphyrin NHC hybrid rhodium(iii) complexes: carbene dissociation and oxidation catalysis

Back to tab navigation

Supplementary files

Publication details

The article was received on 20 Jan 2014, accepted on 05 Feb 2014 and first published on 06 Feb 2014


Article type: Communication
DOI: 10.1039/C4CC00497C
Citation: Chem. Commun., 2014,50, 3488-3490

  •   Request permissions

    Springloaded porphyrin NHC hybrid rhodium(III) complexes: carbene dissociation and oxidation catalysis

    J. Olguín, H. Müller-Bunz and M. Albrecht, Chem. Commun., 2014, 50, 3488
    DOI: 10.1039/C4CC00497C

Search articles by author

Spotlight

Advertisements