Issue 30, 2014

Well-defined molecular uranium(iii) chloride complexes

Abstract

The first anhydrous molecular complexes of uranium(III) chloride, soluble in polar aprotic solvents, are reported, including the structures of the dimeric [UCl3(py)4]2 and the trimetallic [UCl(py)4(μ-Cl)3U(py)2(μ-Cl)3UCl2(py)3].

Graphical abstract: Well-defined molecular uranium(iii) chloride complexes

Supplementary files

Article information

Article type
Communication
Submitted
12 Dec 2013
Accepted
21 Feb 2014
First published
21 Feb 2014
This article is Open Access
Creative Commons BY license

Chem. Commun., 2014,50, 3962-3964

Author version available

Well-defined molecular uranium(III) chloride complexes

H. S. La Pierre, F. W. Heinemann and K. Meyer, Chem. Commun., 2014, 50, 3962 DOI: 10.1039/C3CC49452G

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