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Issue 14, 2014
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An isoelectronic NO dioxygenase reaction using a nonheme iron(III)-peroxo complex and nitrosonium ion

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Abstract

Reaction of a nonheme iron(III)-peroxo complex, [FeIII(14-TMC)(O2)]+, with NO+, a transformation which is essentially isoelectronic with that for nitric oxide dioxygenases [Fe(III)(O2˙) + NO], affords an iron(IV)-oxo complex, [FeIV(14-TMC)(O)]2+, and nitrogen dioxide (NO2), followed by conversion to an iron(III)-nitrato complex, [FeIII(14-TMC)(NO3)(F)]+.

Graphical abstract: An isoelectronic NO dioxygenase reaction using a nonheme iron(iii)-peroxo complex and nitrosonium ion

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Publication details

The article was received on 18 Nov 2013, accepted on 11 Dec 2013 and first published on 13 Dec 2013


Article type: Communication
DOI: 10.1039/C3CC48782B
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Chem. Commun., 2014,50, 1742-1744

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    An isoelectronic NO dioxygenase reaction using a nonheme iron(III)-peroxo complex and nitrosonium ion

    A. Yokoyama, J. E. Han, K. D. Karlin and W. Nam, Chem. Commun., 2014, 50, 1742
    DOI: 10.1039/C3CC48782B

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