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Issue 15, 2014
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Nitronyl nitroxide–metal complexes as metallo-ligands for the construction of hetero-tri-spin (2p–3d–4f) chains

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Abstract

A novel approach for the preparation of hetero-tri-spin magnetic compounds is described. It consists in using preformed metal–nitronyl nitroxide complexes as metallo-ligands in an assembling process involving an additional metal centre. This is illustrated by two unprecedented radical–Cu–Ln chain compounds (Ln = Gd3+, Tb3+).

Graphical abstract: Nitronyl nitroxide–metal complexes as metallo-ligands for the construction of hetero-tri-spin (2p–3d–4f) chains

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Publication details

The article was received on 22 Oct 2013, accepted on 03 Dec 2013 and first published on 09 Jan 2014


Article type: Communication
DOI: 10.1039/C3CC48110G
Citation: Chem. Commun., 2014,50, 1906-1908
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    Nitronyl nitroxide–metal complexes as metallo-ligands for the construction of hetero-tri-spin (2p–3d–4f) chains

    M. Zhu, X. Mei, Y. Ma, L. Li, D. Liao and J. Sutter, Chem. Commun., 2014, 50, 1906
    DOI: 10.1039/C3CC48110G

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