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Issue 100, 2014
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Rim-functionalized cryptophane-111 derivatives via heterocapping, and their xenon complexes

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Abstract

Capping of cyclotriphenolene (3a) by the more available cyclotriguaiacylene (3c) or trisbromocyclotriphenolene (3b) gives the first rim-functionalized cryptophane-111 derivatives. Crystal structures of the xenon complexes reveal high cavity packing coefficients and unprecedentedly short Xe⋯C contacts.

Graphical abstract: Rim-functionalized cryptophane-111 derivatives via heterocapping, and their xenon complexes

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Submitted
09 Oct 2014
Accepted
01 Nov 2014
First published
03 Nov 2014

Chem. Commun., 2014,50, 15905-15908
Article type
Communication
Author version available

Rim-functionalized cryptophane-111 derivatives via heterocapping, and their xenon complexes

A. I. Joseph, G. El-Ayle, C. Boutin, E. Léonce, P. Berthault and K. T. Holman, Chem. Commun., 2014, 50, 15905
DOI: 10.1039/C4CC08001G

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