Issue 96, 2014
From the journal:

Chemical Communications

Heterometallic cluster-based indium–organic frameworks†

Jinjie Qian,ab   Feilong Jiang,a   Kongzhao Su,ab   Jie Pan,ab   Zhenzhen Xue,ab   Linfeng Liang,ab   Partha Pratim Baga  and  Maochun Hong*a  

* Corresponding authors

a Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China
E-mail: hmc@fjirsm.ac.cn
Fax: +86-591-83794946
Tel: +86-591-83792460

b University of the Chinese Academy of Sciences, Beijing, China

Abstract

With the help of the ligand-oriented method, we have successfully embedded independent copper-based units into the indium–organic framework system for the first time, in which the Cu4I4 clusters and In3O(CO2)6 clusters coexist. This heterometallic cluster-based framework InOF-8 has a large porosity with extra-open channels along the c-axis, and its sorption capacity has also been investigated.

Graphical abstract: Heterometallic cluster-based indium–organic frameworks

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Article information

DOI
https://doi.org/10.1039/C4CC07611G
Article type
Communication
Submitted
26 Sep 2014
Accepted
16 Oct 2014
First published
16 Oct 2014

Chem. Commun., 2014,50, 15224-15227

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Heterometallic cluster-based indium–organic frameworks

J. Qian, F. Jiang, K. Su, J. Pan, Z. Xue, L. Liang, P. P. Bag and M. Hong, Chem. Commun., 2014, 50, 15224 DOI: 10.1039/C4CC07611G

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