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Issue 95, 2014
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The solvent effect in an axially symmetric FeIII4 single-molecule magnet

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Abstract

A pair of enantiopure FeIII4 SMMs with axial symmetry was synthesized and characterized by magnetization and high-frequency electron paramagnetic resonance methods. The results reveal that the axial symmetry of the structure is broken by the interaction of FeIII4 with the disordered solvent molecules.

Graphical abstract: The solvent effect in an axially symmetric FeIII4 single-molecule magnet

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Supplementary files

Article information


Submitted
25 Sep 2014
Accepted
13 Oct 2014
First published
13 Oct 2014

Chem. Commun., 2014,50, 15090-15093
Article type
Communication
Author version available

The solvent effect in an axially symmetric FeIII4 single-molecule magnet

Y. Zhu, T. Yin, S. Jiang, A. Barra, W. Wernsdorfer, P. Neugebauer, R. Marx, M. Dörfel, B. Wang, Z. Wu, J. V. Slageren and S. Gao, Chem. Commun., 2014, 50, 15090
DOI: 10.1039/C4CC07580C

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