Issue 94, 2014
From the journal:

Chemical Communications

Novel zwitterionic complexes arising from the coordination of an ambiphilic phosphorus–aluminum ligand to gold†

Marc Devillard,a   Emmanuel Nicolas, ORCID logo b   Christian Appelt,c   Jana Backs,c   Sonia Mallet-Ladeira,d   Ghenwa Bouhadir,*a   J. Chris Slootweg,*b   Werner Uhl*c  and  Didier Bourissou*a  

* Corresponding authors

a Université de Toulouse, UPS, LHFA, 118 route de Narbonne, 31062 Toulouse, France and CNRS, LHFA, UMR 5069, 31062 Toulouse, France
E-mail: bouhadir@chimie.ups-tlse.fr, dbouriss@chimie.ups-tlse.fr
Fax: +33 (0)5 61 55 82 04
Tel: +33 (0)5 61 55 68 03

b Department of Chemistry and Pharmaceutical Sciences, VU University Amsterdam, De Boelelaan 1083, 1081 HV Amsterdam, The Netherlands
E-mail: j.c.slootweg@vu.nl

c Institut für Anorganische und Analytische Chemie der Westfälischen Wilhelms-Universität Münster, Corrensstrasse 30, 48149 Münster, Germany
E-mail: uhlw@uni-muenster.de

d Université Paul Sabatier, Institut de Chimie de Toulouse (FR 2599), 118 route de Narbonne, 31062 Toulouse cedex 9, France

Abstract

Coordination of Mes2PC([double bond, length as m-dash]CHPh)AltBu2 to metal chlorides has been studied. Bridging P→M–Cl→Al coordinations were observed with Rh and Pd fragments, while chloride abstraction systematically occurred with gold. The resulting zwitterionic complexes have been fully characterized and analyzed by DFT calculations.

Graphical abstract: Novel zwitterionic complexes arising from the coordination of an ambiphilic phosphorus–aluminum ligand to gold

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Article information

DOI
https://doi.org/10.1039/C4CC06992G
Article type
Communication
Submitted
04 Sep 2014
Accepted
24 Sep 2014
First published
06 Oct 2014

Chem. Commun., 2014,50, 14805-14808

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Novel zwitterionic complexes arising from the coordination of an ambiphilic phosphorus–aluminum ligand to gold

M. Devillard, E. Nicolas, C. Appelt, J. Backs, S. Mallet-Ladeira, G. Bouhadir, J. C. Slootweg, W. Uhl and D. Bourissou, Chem. Commun., 2014, 50, 14805 DOI: 10.1039/C4CC06992G

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