Issue 90, 2014
From the journal:

Chemical Communications

Silver-catalyzed carbon–phosphorus functionalization of N-(p-methoxyaryl)propiolamides coupled with dearomatization: access to phosphorylated aza-decenones†

Li-Jing Wang,a   An-Qi Wang,a   Yu Xia,a   Xin-Xing Wu,a   Xue-Yuan Liua  and  Yong-Min Liang*a  

* Corresponding authors

a State Key Laboratory of Applied Organic Chemistry, Lanzhou University 730000, P. R. China
E-mail: liangym@lzu.edu.cn

Abstract

Silver-catalyzed cascade difunctionalization of N-(p-methoxyaryl)propiolamides coupled with dearomatization was achieved and used to regiospecifically construct a variety of phosphorylated aza-decenones bearing adjacent quaternary stereocenters under mild conditions in moderate to excellent yields.

Graphical abstract: Silver-catalyzed carbon–phosphorus functionalization of N-(p-methoxyaryl)propiolamides coupled with dearomatization: access to phosphorylated aza-decenones

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Article information

DOI
https://doi.org/10.1039/C4CC06923D
Article type
Communication
Submitted
02 Sep 2014
Accepted
20 Sep 2014
First published
22 Sep 2014

Chem. Commun., 2014,50, 13998-14001

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Silver-catalyzed carbon–phosphorus functionalization of N-(p-methoxyaryl)propiolamides coupled with dearomatization: access to phosphorylated aza-decenones

L. Wang, A. Wang, Y. Xia, X. Wu, X. Liu and Y. Liang, Chem. Commun., 2014, 50, 13998 DOI: 10.1039/C4CC06923D

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