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Silver-catalyzed cascade difunctionalization of N-(p-methoxyaryl)propiolamides coupled with dearomatization was achieved and used to regiospecifically construct a variety of phosphorylated aza-decenones bearing adjacent quaternary stereocenters under mild conditions in moderate to excellent yields.

Graphical abstract: Silver-catalyzed carbon–phosphorus functionalization of N-(p-methoxyaryl)propiolamides coupled with dearomatization: access to phosphorylated aza-decenones

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