Issue 93, 2014
From the journal:

Chemical Communications

Panchromatic absorbers for solar light-harvesting†

Eric J. Alexy,a   Jonathan M. Yuen,b   Vanampally Chandrashaker,a   James R. Diers,c   Christine Kirmaier,b   David F. Bocian,*c   Dewey Holten*b  and  Jonathan S. Lindsey*a  

* Corresponding authors

a Department of Chemistry, North Carolina State University, Raleigh, North Carolina 27695-8204, USA
E-mail: jlindsey@ncsu.edu

b Department of Chemistry, Washington University, St. Louis, Missouri 63130-4889, USA
E-mail: holten@wuchem.wustl.edu

c Department of Chemistry, University of California, Riverside, California 92521-0403, USA
E-mail: david.bocian@ucr.edu

Abstract

A set of panchromatic absorbers exhibiting long excited-state lifetimes in both polar and nonpolar media has been prepared. The architectures are based on a porphyrin strongly coupled electronically to 1−4 perylene–monoimides via ethyne linkers. The constructs should find utility in molecular solar-conversion systems.

Graphical abstract: Panchromatic absorbers for solar light-harvesting

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Article information

DOI
https://doi.org/10.1039/C4CC06853J
Article type
Communication
Submitted
30 Aug 2014
Accepted
06 Oct 2014
First published
13 Oct 2014

Chem. Commun., 2014,50, 14512-14515

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Panchromatic absorbers for solar light-harvesting

E. J. Alexy, J. M. Yuen, V. Chandrashaker, J. R. Diers, C. Kirmaier, D. F. Bocian, D. Holten and J. S. Lindsey, Chem. Commun., 2014, 50, 14512 DOI: 10.1039/C4CC06853J

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