Jump to main content
Jump to site search

Issue 85, 2014
Previous Article Next Article

Room temperature alkynylation of H-phosphi(na)tes and secondary phosphine oxides with ethynylbenziodoxolone (EBX) reagents

Author affiliations

Abstract

Highly efficient protocols for the alkynylation of H-phosphi(na)tes and secondary phosphine oxides with silyl, aryl and alkyl ethynyl-benziodoxolone (EBX) reagents are reported. Alkynyl phosphorus compounds were obtained in 69–93% yield without the need for a transition metal catalyst at room temperature under open flask conditions.

Graphical abstract: Room temperature alkynylation of H-phosphi(na)tes and secondary phosphine oxides with ethynylbenziodoxolone (EBX) reagents

Back to tab navigation

Supplementary files

Publication details

The article was received on 30 Aug 2014, accepted on 09 Sep 2014 and first published on 12 Sep 2014


Article type: Communication
DOI: 10.1039/C4CC06851C
Author version
available:
Download author version (PDF)
Citation: Chem. Commun., 2014,50, 12923-12926
  •   Request permissions

    Room temperature alkynylation of H-phosphi(na)tes and secondary phosphine oxides with ethynylbenziodoxolone (EBX) reagents

    C. C. Chen and J. Waser, Chem. Commun., 2014, 50, 12923
    DOI: 10.1039/C4CC06851C

Search articles by author

Spotlight

Advertisements