Issue 87, 2014
From the journal:

Chemical Communications

Clathrates of TETROL: selective inclusion of methylcyclohexanones in their energetically unfavorable axial methyl conformations†

B. Barton,*a   M. R. Caira,*b   E. C. Hosten,a   C. W. McClelanda  and  S. Weitza  

* Corresponding authors

a Department of Chemistry, Nelson Mandela Metropolitan University, PO Box 77000, Port Elizabeth 6031, South Africa
E-mail: benita.barton@nmmu.ac.za
Fax: (+)27 41 504 4236

b Department of Chemistry, University of Cape Town, Rondebosch 7701, South Africa
E-mail: mino.caira@uct.ac.za
Fax: (+)27 21 650 5195

Abstract

3- and 4-Methylcyclohexanone have been isolated exclusively as their energetically disfavoured axial conformers in the host–guest complexes formed upon recrystallization of the novel optically pure host compound, (+)-(2R,3R)-1,1,4,4-tetraphenylbutane-1,2,3,4-tetraol (TETROL), from these cycloalkanones.

Graphical abstract: Clathrates of TETROL: selective inclusion of methylcyclohexanones in their energetically unfavorable axial methyl conformations

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Article information

DOI
https://doi.org/10.1039/C4CC06826B
Article type
Communication
Submitted
29 Aug 2014
Accepted
13 Sep 2014
First published
18 Sep 2014

Chem. Commun., 2014,50, 13353-13355

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Clathrates of TETROL: selective inclusion of methylcyclohexanones in their energetically unfavorable axial methyl conformations

B. Barton, M. R. Caira, E. C. Hosten, C. W. McCleland and S. Weitz, Chem. Commun., 2014, 50, 13353 DOI: 10.1039/C4CC06826B

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