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Issue 89, 2014
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Potential-controlled rotaxane molecular shuttles based on electron-deficient macrocyclic complexes

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Abstract

This communication reports a novel sandwich-like rotaxane shuttle, which exhibits a unique mode of potential-controlled behaviour. Two dynamic processes occur simultaneously – conformational “unfolding” of the DADA stack accompanies translocation of the ring over the rotaxane's axle.

Graphical abstract: Potential-controlled rotaxane molecular shuttles based on electron-deficient macrocyclic complexes

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Article information


Submitted
26 Aug 2014
Accepted
11 Sep 2014
First published
11 Sep 2014

Chem. Commun., 2014,50, 13718-13721
Article type
Communication

Potential-controlled rotaxane molecular shuttles based on electron-deficient macrocyclic complexes

M. Woźny, J. Pawłowska, K. M. Tomczyk, R. Bilewicz and B. Korybut-Daszkiewicz, Chem. Commun., 2014, 50, 13718
DOI: 10.1039/C4CC06718E

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