Phosphines are fundamentally important to the fine chemicals, pharmaceutical and agrochemical industries. Reported is the first example of alkene hydrophosphination using a designed iron pre-catalyst which yields the anti-Markovnikov products in high yield at room temperature. The phosphine products are excellent pro-ligands for Fe-catalyzed Negishi cross-coupling.
K. J. Gallagher and R. L. Webster, Chem. Commun., 2014, 50, 12109 DOI: 10.1039/C4CC06526C
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