Issue 88, 2014
From the journal:

Chemical Communications

Thermodynamics of halogen bonded monolayer self-assembly at the liquid–solid interface†

W. Song,ab   N. Martsinovich,c   W. M. Hecklabd  and  M. Lackinger*abd  

* Corresponding authors

a Department of Physics, Technische Universität München, James-Franck-Str. 1, 85748 Garching, Germany
E-mail: markus@lackinger.org

b Nanosystems-Initiative-Munich and Center for NanoScience (CeNS), Schellingstr. 4, 80799 Munich, Germany

c Department of Chemistry, University of Sheffield, Sheffield S3 7HF, UK

d Deutsches Museum, Museumsinsel 1, 80538 Munich, Germany

Abstract

Monolayer self-assembly of a hexabrominated, three-fold symmetric aromatic molecule is studied at the heptanoic acid–graphite interface. Thermodynamical insights are obtained from an adapted Born–Haber cycle that is utilized to derive the overall enthalpy change including solvent effects. Comparison with theoretical entropy estimates suggests a minor influence of solvation.

Graphical abstract: Thermodynamics of halogen bonded monolayer self-assembly at the liquid–solid interface

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Article information

DOI
https://doi.org/10.1039/C4CC06251E
Article type
Communication
Submitted
09 Aug 2014
Accepted
08 Sep 2014
First published
09 Sep 2014

Chem. Commun., 2014,50, 13465-13468

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Thermodynamics of halogen bonded monolayer self-assembly at the liquid–solid interface

W. Song, N. Martsinovich, W. M. Heckl and M. Lackinger, Chem. Commun., 2014, 50, 13465 DOI: 10.1039/C4CC06251E

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