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Issue 94, 2014
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Cerium tetrakis(diisopropylamide) – a useful precursor for cerium(iv) chemistry

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Abstract

Homoleptic cerium(IV) diisopropylamide was synthesized via oxidation of ate complex Ce(NiPr2)4Li(thf) with trityl chloride or hexachloroethane. Due to its ready accessibility, and high pKa value of the proligand HNiPr2, Ce(NiPr2)4 features a promising candidate for protonolysis reactions, as shown for the synthesis of dimeric cerium(IV) tetrakis(1,1,3,3-N,N,N′,N′-tetramethylguanidinate).

Graphical abstract: Cerium tetrakis(diisopropylamide) – a useful precursor for cerium(iv) chemistry

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Article information


Submitted
08 Aug 2014
Accepted
07 Oct 2014
First published
08 Oct 2014

Chem. Commun., 2014,50, 14763-14766
Article type
Communication

Cerium tetrakis(diisopropylamide) – a useful precursor for cerium(IV) chemistry

D. Schneider, T. Spallek, C. Maichle-Mössmer, K. W. Törnroos and R. Anwander, Chem. Commun., 2014, 50, 14763
DOI: 10.1039/C4CC06228K

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