Issue 89, 2014
From the journal:

Chemical Communications

Catalytic enantioselective bromoamination of allylic alcohols†

Juan Qi,‡a   Guo-Tao Fan,‡a   Jie Chen,a   Ming-Hui Sun,a   Yu-Ting Donga  and  Ling Zhou*a  

* Corresponding authors

a Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry & Materials Science, Northwest University, Xi'an 710069, P. R. China
E-mail: zhoul@nwu.edu.cn

Abstract

An enantioselective bromoamination of allylic alcohols has been developed for the first time using a newly designed cinchona-derived thiourea as the catalyst and N,N-dibromo-4-nitrobenzenesulfonamide as a bromine and amine source.

Graphical abstract: Catalytic enantioselective bromoamination of allylic alcohols

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Article information

DOI
https://doi.org/10.1039/C4CC05772D
Article type
Communication
Submitted
24 Jul 2014
Accepted
18 Sep 2014
First published
18 Sep 2014

Chem. Commun., 2014,50, 13841-13844

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Catalytic enantioselective bromoamination of allylic alcohols

J. Qi, G. Fan, J. Chen, M. Sun, Y. Dong and L. Zhou, Chem. Commun., 2014, 50, 13841 DOI: 10.1039/C4CC05772D

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