A single-chain magnet based on linear [MnIII2MnII] units

Constantina Papatriantafyllopoulou; Sotiris Zartilas; Manolis J. Manos; Céline Pichon; Rodolphe Clérac; Anastasios J. Tasiopoulos

doi:10.1039/C4CC05687F

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A single-chain magnet based on linear [Mn^III₂Mn^II] units†

Constantina Papatriantafyllopoulou,^a Sotiris Zartilas,^a Manolis J. Manos,‡^a Céline Pichon,^bc Rodolphe Clérac*^bc and Anastasios J. Tasiopoulos*^a

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* Corresponding authors

^a Department of Chemistry, University of Cyprus, 1678 Nicosia, Cyprus
E-mail: atasio@ucy.ac.cy
Fax: +357 22892801
Tel: +357 22892765

^b CNRS, CRPP, UPR 8641, F-33600 Pessac, France
E-mail: clerac@crpp-bordeaux.cnrs.fr

^c Univ. Bordeaux, CRPP, UPR 8641, F-33600 Pessac, France

Abstract

The synthesis, structural characterization and magnetic properties of a 1D coordination polymer based on a linear mixed valent [Mn^III₂Mn^II] repeating unit are described. It displays single-chain magnet (SCM) behaviour with an energy barrier of ∼38 K and represents the first example of a mixed valent Mn–carboxylate SCM with a linear architecture.

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DOI: https://doi.org/10.1039/C4CC05687F
Article type: Communication
Submitted: 22 Jul 2014
Accepted: 19 Sep 2014
First published: 30 Sep 2014
This article is Open Access

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Chem. Commun., 2014,50, 14873-14876

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A single-chain magnet based on linear [Mn^III₂Mn^II] units

C. Papatriantafyllopoulou, S. Zartilas, M. J. Manos, C. Pichon, R. Clérac and A. J. Tasiopoulos, Chem. Commun., 2014, 50, 14873 DOI: 10.1039/C4CC05687F

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