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Issue 88, 2014
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A nickel dimethyl glyoximato complex to form nickel based nanoparticles for electrocatalytic H2 production

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Abstract

We report on the electrochemical alteration of a nickel(II) bis-glyoximato complex into nickel-based nanoparticles at a glassy carbon electrode under acid reducing conditions. These particles show electrocatalytic activity towards hydrogen production at +410 mV compared to the bare glassy carbon electrode. Mechanistic insights are discussed based on DFT calculations.

Graphical abstract: A nickel dimethyl glyoximato complex to form nickel based nanoparticles for electrocatalytic H2 production

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Publication details

The article was received on 11 Jul 2014, accepted on 08 Sep 2014 and first published on 10 Sep 2014


Article type: Communication
DOI: 10.1039/C4CC05355A
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Citation: Chem. Commun., 2014,50, 13514-13516
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    A nickel dimethyl glyoximato complex to form nickel based nanoparticles for electrocatalytic H2 production

    S. Cherdo, S. E. Ghachtouli, M. Sircoglou, F. Brisset, M. Orio and A. Aukauloo, Chem. Commun., 2014, 50, 13514
    DOI: 10.1039/C4CC05355A

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