Issue 85, 2014
From the journal:

Chemical Communications

Hydride transfer from NADH analogues to a nonheme manganese(iv)–oxo complex via rate-determining electron transfer†

Heejung Yoon,a   Yong-Min Lee,b   Wonwoo Nam*b  and  Shunichi Fukuzumi*ab  

* Corresponding authors

a Department of Material and Life Science Graduate School of Engineering, Osaka University and ALCA (JST), 2-1 Yamada-oka, Suita, Osaka 565-0871, Japan
E-mail: fukuzumi@chem.eng.osaka-u.jp

b Department of Chemistry and Nano Science, Ewha Womans University, Seoul, Korea
E-mail: wwnam@ewha.ac.kr

Abstract

Hydride transfer from NADH analogues to a nonheme Mn(IV)–oxo complex, [(Bn-TPEN)MnIV(O)]2+, proceeds via a rate-determining electron transfer step with no deuterium kinetic isotope effect (KIE = 1.0 ± 0.1); a charge-transfer complex formed between the MnIV(O) complex and NADH analogues is involved in the hydride transfer reaction.

Graphical abstract: Hydride transfer from NADH analogues to a nonheme manganese(iv)–oxo complex via rate-determining electron transfer

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Article information

DOI
https://doi.org/10.1039/C4CC05313C
Article type
Communication
Submitted
10 Jul 2014
Accepted
18 Aug 2014
First published
01 Sep 2014

Chem. Commun., 2014,50, 12944-12946

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Hydride transfer from NADH analogues to a nonheme manganese(IV)–oxo complex via rate-determining electron transfer

H. Yoon, Y. Lee, W. Nam and S. Fukuzumi, Chem. Commun., 2014, 50, 12944 DOI: 10.1039/C4CC05313C

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