Issue 91, 2014

Ruthenium-catalyzed double-fold C–H tertiary alkoxycarbonylation of arenes using di-tert-butyl dicarbonate

Abstract

An efficient ruthenium-catalyzed double-fold C–H alkoxycarbonylation of arenes was developed using di-tert-butyl dicarbonate as the tertiary esterification reagent, which leads to a direct route to valuable 2,6-dicarboxylated products.

Graphical abstract: Ruthenium-catalyzed double-fold C–H tertiary alkoxycarbonylation of arenes using di-tert-butyl dicarbonate

Supplementary files

Article information

Article type
Communication
Submitted
05 Jul 2014
Accepted
12 Sep 2014
First published
17 Sep 2014

Chem. Commun., 2014,50, 14129-14132

Author version available

Ruthenium-catalyzed double-fold C–H tertiary alkoxycarbonylation of arenes using di-tert-butyl dicarbonate

X. Hong, H. Wang, B. Liu and B. Xu, Chem. Commun., 2014, 50, 14129 DOI: 10.1039/C4CC05173D

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