An efficient formation of acetoin from acetaldehyde was achieved under thiazolylidene catalysis. High yields and TON were achieved. Its sufficient tolerance toward ethanol and moisture renders it a practical key step of the ethanol upgrading process. A new type of solid supported thiazolylidene catalyst was designed to make catalyst recycling achievable.
L. Gu, T. Lu, X. Li and Y. Zhang, Chem. Commun., 2014, 50, 12308 DOI: 10.1039/C4CC04831H
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