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Issue 74, 2014
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Facile synthesis of ultra-small rhenium nanoparticles

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Abstract

Ultra-small monodisperse rhenium nanoparticles (Re NPs; ca. 1.0–1.2 nm) were easily prepared by reducing the organometallic complex [Re2(C3H5)4] under a dihydrogen atmosphere under mild reaction conditions (3 bar H2; 120 °C). The particles can be stabilized by a ligand, hexadecylamine, or a polymer, polyvinylpyrrolidone and accommodate surface hydrides.

Graphical abstract: Facile synthesis of ultra-small rhenium nanoparticles

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Publication details

The article was received on 24 Jun 2014, accepted on 23 Jul 2014 and first published on 24 Jul 2014


Article type: Communication
DOI: 10.1039/C4CC04816D
Citation: Chem. Commun., 2014,50, 10809-10811
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    Facile synthesis of ultra-small rhenium nanoparticles

    T. Ayvalı, P. Lecante, P. Fazzini, A. Gillet, K. Philippot and B. Chaudret, Chem. Commun., 2014, 50, 10809
    DOI: 10.1039/C4CC04816D

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