Issue 73, 2014
From the journal:

Chemical Communications

A divalent heteroleptic lanthanoid fluoride complex stabilised by the tetraphenylcyclopentadienyl ligand, arising from C–F activation of pentafluorobenzene†

G. B. Deacon,*a   F. Jaroschik,*b   P. C. Junk*c  and  R. P. Kellya  

* Corresponding authors

a School of Chemistry, Monash University, Clayton 3800, Australia
E-mail: glen.deacon@monash.edu

b Institut de Chimie Moléculaire de Reims, UMR CNRS 7312, Université de Reims, BP 1039, 51687 Reims Cedex 2, France
E-mail: florian.jaroschik@univ-reims.fr

c School of Pharmacy and Molecular Sciences, James Cook University, Townsville 4811, Qld, Australia
E-mail: peter.junk@jcu.edu.au

Abstract

The divalent heteroleptic lanthanoid fluoride complex, [Yb(C5Ph4H)(μ-F)(thf)2]2, as well as [Yb(C5Ph4H)2(thf)] and [Yb(C5Ph4H)(C6F5)(thf)2] were obtained from reactions of ytterbium metal with Hg(C6F5)2 and tetraphenylcyclopentadiene under different conditions, and C–F activation of C6F5H by Yb metal was observed.

Graphical abstract: A divalent heteroleptic lanthanoid fluoride complex stabilised by the tetraphenylcyclopentadienyl ligand, arising from C–F activation of pentafluorobenzene

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Article information

DOI
https://doi.org/10.1039/C4CC04427D
Article type
Communication
Submitted
11 Jun 2014
Accepted
22 Jul 2014
First published
22 Jul 2014

Chem. Commun., 2014,50, 10655-10657

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A divalent heteroleptic lanthanoid fluoride complex stabilised by the tetraphenylcyclopentadienyl ligand, arising from C–F activation of pentafluorobenzene

G. B. Deacon, F. Jaroschik, P. C. Junk and R. P. Kelly, Chem. Commun., 2014, 50, 10655 DOI: 10.1039/C4CC04427D

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