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Issue 72, 2014
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Incorporation of iron hydrogenase active sites into a highly stable metal–organic framework for photocatalytic hydrogen generation

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Abstract

A new biomimetic heterogeneous photocatalyst ([FeFe]@ZrPF) has been synthesized through the incorporation of homogeneous complex 1 [(í-SCH2)2NC(O)C5H4N]–[Fe2(CO)6] into the highly robust zirconium-porphyrin based metal–organic framework (ZrPF). The immobilized biomimetic [Fe2S2] catalyst inside the MOF shows great improvement in hydrogen generation compared to the reference homogeneous catalyst complex 1.

Graphical abstract: Incorporation of iron hydrogenase active sites into a highly stable metal–organic framework for photocatalytic hydrogen generation

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Publication details

The article was received on 23 May 2014, accepted on 25 Jun 2014 and first published on 25 Jul 2014


Article type: Communication
DOI: 10.1039/C4CC03946G
Citation: Chem. Commun., 2014,50, 10390-10393
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    Incorporation of iron hydrogenase active sites into a highly stable metal–organic framework for photocatalytic hydrogen generation

    K. Sasan, Q. Lin, C. Mao and P. Feng, Chem. Commun., 2014, 50, 10390
    DOI: 10.1039/C4CC03946G

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