Issue 68, 2014
From the journal:

Chemical Communications

Mechanochemical lithiation of layered polysilane†

Masataka Ohashi,*a   Hideyuki Nakano,ab   Tetsuya Morishita,c   Michelle J. S. Spencer,d   Yuka Ikemoto,e   Chihiro Yogif  and  Toshiaki Ohtaf  

* Corresponding authors

a Toyota Central R&D Laboratories, Inc., Nagakute, Aichi, Japan
E-mail: m-ohashi@mosk.tytlabs.co.jp

b Japan Science and Technology Agency, PRESTO, Kawaguchi, Saitama, Japan

c Nanosystem Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), Central 2, 1-1-1 Umezono, Tsukuba, Ibaraki, Japan

d School of Applied Sciences, RMIT University, GPO Box 2476, Melbourne, Victoria, Australia

e SPring-8 Japan Synchrotron Radiation Research Institute (JASRI), 1-1-1 Kouto, Sayo, Hyogo, Japan

f SR Center, Ritsumeikan University, 1-1-1 Noji-Higashi, Kusatsu, Shiga, Japan

Abstract

Lithiated polysilane was synthesized by the mechanochemical reaction of layered polysilane with metallic lithium. The resulting dark green powder formed a Si–Li bond on the surface and demonstrated electroconductivity.

Graphical abstract: Mechanochemical lithiation of layered polysilane

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Article information

DOI
https://doi.org/10.1039/C4CC03850A
Article type
Communication
Submitted
20 May 2014
Accepted
08 Jul 2014
First published
08 Jul 2014

Chem. Commun., 2014,50, 9761-9764

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Mechanochemical lithiation of layered polysilane

M. Ohashi, H. Nakano, T. Morishita, M. J. S. Spencer, Y. Ikemoto, C. Yogi and T. Ohta, Chem. Commun., 2014, 50, 9761 DOI: 10.1039/C4CC03850A

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