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Issue 75, 2014
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A kinetically protected pyrene: molecular design, bright blue emission in the crystalline state and aromaticity relocation in its dicationic species

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Abstract

Sterically congested tetraarylpyrenes exhibited emission in both solution and the solid state. The monocationic species of pyrene 1 could be isolated because of the reasonably protected system. The aromaticity of 1 relocates from the biphenyl part to the naphthalene unit upon two-electron oxidation.

Graphical abstract: A kinetically protected pyrene: molecular design, bright blue emission in the crystalline state and aromaticity relocation in its dicationic species

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Article information


Submitted
14 May 2014
Accepted
03 Jul 2014
First published
03 Jul 2014

Chem. Commun., 2014,50, 10956-10958
Article type
Communication
Author version available

A kinetically protected pyrene: molecular design, bright blue emission in the crystalline state and aromaticity relocation in its dicationic species

A. Matsumoto, M. Suzuki, D. Kuzuhara, J. Yuasa, T. Kawai, N. Aratani and H. Yamada, Chem. Commun., 2014, 50, 10956
DOI: 10.1039/C4CC03645J

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