Issue 59, 2014

AgSbF6-controlled diastereodivergence in alkyne hydroarylation: facile access to Z- and E-alkenyl arenes

Abstract

AgSbF6-controlled diastereodivergent hydroarylation reactions were developed. Unprecedented and remarkable switching of the E/Z-stereoselectivity could be obtained by adjusting the AgSbF6 loading.

Graphical abstract: AgSbF6-controlled diastereodivergence in alkyne hydroarylation: facile access to Z- and E-alkenyl arenes

Supplementary files

Article information

Article type
Communication
Submitted
13 May 2014
Accepted
03 Jun 2014
First published
04 Jun 2014

Chem. Commun., 2014,50, 8028-8031

AgSbF6-controlled diastereodivergence in alkyne hydroarylation: facile access to Z- and E-alkenyl arenes

M. Min, D. Kim and S. Hong, Chem. Commun., 2014, 50, 8028 DOI: 10.1039/C4CC03602F

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