Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance work on Wednesday 27th March 2019 from 11:00 AM to 1:00 PM (GMT).

During this time our website performance may be temporarily affected. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 58, 2014
Previous Article Next Article

An efficient synthetic route to stable bis(carbene)borylenes [(L1)(L2)BH]

Author affiliations

Abstract

Two-electron reduction of bis(carbene) boronium salts allows for the preparation of unsymmetrically substituted nucleophilic boron derivatives of type (L1)(L2)BH, which are characterized by X-ray crystallography. A single electron reduction of the same starting materials leads to the corresponding boron-centered radical cations (L1)(L2)BH˙+, X.

Graphical abstract: An efficient synthetic route to stable bis(carbene)borylenes [(L1)(L2)BH]

Back to tab navigation

Supplementary files

Publication details

The article was received on 08 May 2014, accepted on 03 Jun 2014 and first published on 04 Jun 2014


Article type: Communication
DOI: 10.1039/C4CC03497J
Author version
available:
Download author version (PDF)
Citation: Chem. Commun., 2014,50, 7837-7839

  •   Request permissions

    An efficient synthetic route to stable bis(carbene)borylenes [(L1)(L2)BH]

    D. A. Ruiz, M. Melaimi and G. Bertrand, Chem. Commun., 2014, 50, 7837
    DOI: 10.1039/C4CC03497J

Search articles by author

Spotlight

Advertisements