The first example of 1,2,4,3-triazaborole-based oxoborane has been synthesized via hydrogen migration upon the coordination of AlCl3 to the corresponding borinic acid. X-ray diffraction analysis and computational study disclosed the partial B![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
O double-bond property.
Y. K. Loh, C. C. Chong, R. Ganguly, Y. Li, D. Vidovic and R. Kinjo, Chem. Commun., 2014, 50, 8561 DOI: 10.1039/C4CC03379E
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