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Issue 87, 2014
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Quantifying chloride binding and salt extraction with poly(methyl methacrylate) copolymers bearing aryl-triazoles as anion receptor side chains

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Abstract

Copolymers of methyl methacrylate and aryl-triazole based anion receptors were quantitatively analyzed. Transfer of structural features (1 : 1 and 2 : 1 complexes) and Cl affinities from the parent receptors was demonstrated. Cl-induced cross-linking changed the polymer's hydrodynamic radius. Extraction of tetrapropylammonium Cl from water to dichloromethane was enhanced over PMMA.

Graphical abstract: Quantifying chloride binding and salt extraction with poly(methyl methacrylate) copolymers bearing aryl-triazoles as anion receptor side chains

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Publication details

The article was received on 05 May 2014, accepted on 29 Jul 2014 and first published on 18 Sep 2014


Article type: Communication
DOI: 10.1039/C4CC03362K
Citation: Chem. Commun., 2014,50, 13285-13288
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    Quantifying chloride binding and salt extraction with poly(methyl methacrylate) copolymers bearing aryl-triazoles as anion receptor side chains

    K. P. McDonald, B. Qiao, E. B. Twum, S. Lee, P. J. Gamache, C. Chen, Y. Yi and A. H. Flood, Chem. Commun., 2014, 50, 13285
    DOI: 10.1039/C4CC03362K

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