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Issue 87, 2014
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Quantifying chloride binding and salt extraction with poly(methyl methacrylate) copolymers bearing aryl-triazoles as anion receptor side chains

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Abstract

Copolymers of methyl methacrylate and aryl-triazole based anion receptors were quantitatively analyzed. Transfer of structural features (1 : 1 and 2 : 1 complexes) and Cl affinities from the parent receptors was demonstrated. Cl-induced cross-linking changed the polymer's hydrodynamic radius. Extraction of tetrapropylammonium Cl from water to dichloromethane was enhanced over PMMA.

Graphical abstract: Quantifying chloride binding and salt extraction with poly(methyl methacrylate) copolymers bearing aryl-triazoles as anion receptor side chains

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Supplementary files

Article information


Submitted
05 May 2014
Accepted
29 Jul 2014
First published
18 Sep 2014

Chem. Commun., 2014,50, 13285-13288
Article type
Communication

Quantifying chloride binding and salt extraction with poly(methyl methacrylate) copolymers bearing aryl-triazoles as anion receptor side chains

K. P. McDonald, B. Qiao, E. B. Twum, S. Lee, P. J. Gamache, C. Chen, Y. Yi and A. H. Flood, Chem. Commun., 2014, 50, 13285
DOI: 10.1039/C4CC03362K

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