Almost perfect embedding of SnO2 nanocrystallites in carbon nanopores was achieved by in situ synthesis using vaporized SnCl2 and silica opal-derived nanoporous carbons. The reversibility of SnO2–Sn conversion and Sn–Li alloying/de-alloying reactions was greatly enhanced by the confinement in regulated carbon nanospace.
S. Oro, K. Urita and I. Moriguchi, Chem. Commun., 2014, 50, 7143 DOI: 10.1039/C4CC02716G
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