A synthetic model for the oxygen-evolving complex in Sr2+-containing photosystem II

Changhui Chen; Chunxi Zhang; Hongxing Dong; Jingquan Zhao

doi:10.1039/C4CC02349H

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A synthetic model for the oxygen-evolving complex in Sr²⁺-containing photosystem II†

Changhui Chen,^a Chunxi Zhang,*^b Hongxing Dong*^a and Jingquan Zhao^b

Author affiliations

* Corresponding authors

^a Polymer Materials Research Center, Key Laboratory of Superlight Materials & Surface Technology of Ministry of Education, College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, China
E-mail: dhongxing@hrbeu.edu.cn
Tel: +86-451-82568191

^b Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
E-mail: chunxizhang@iccas.ac.cn
Fax: +86-10-82617315
Tel: +86-10-82617053

Abstract

A novel heterometallic MnSr complex containing the Mn₃SrO₄ cuboidal moiety and all types of μ-O²⁻ moieties observed in the oxygen-evolving complex (OEC) in Sr²⁺-containing photosystem II (PSII) has been synthesized and characterized, which provides a new synthetic model of the OEC.

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Article information

DOI: https://doi.org/10.1039/C4CC02349H
Article type: Communication
Submitted: 30 Mar 2014
Accepted: 25 Apr 2014
First published: 25 Apr 2014

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Chem. Commun., 2014,50, 9263-9265

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A synthetic model for the oxygen-evolving complex in Sr²⁺-containing photosystem II

C. Chen, C. Zhang, H. Dong and J. Zhao, Chem. Commun., 2014, 50, 9263 DOI: 10.1039/C4CC02349H

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