Iron-catalyzed alkylation of internal olefins, that is, α-oxo ketene dithioacetals, was successfully realized by using styrenes as the alkylating reagents. Highly functionalized tetrasubstituted olefins were prepared in moderate to high yields.
Q. Yang, P. Wu, J. Chen and Z. Yu, Chem. Commun., 2014, 50, 6337 DOI: 10.1039/C4CC02264E
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