Issue 58, 2014

Acid-free regioselective aminocarbonylation of alkenes

Abstract

An efficient method for the synthesis of N-aryl monosubstituted carboxamides via the Pd-catalyzed carbonylation of alkenes with CO and amines is described. Mechanistic insights for this highly selective reaction are provided.

Graphical abstract: Acid-free regioselective aminocarbonylation of alkenes

Supplementary files

Article information

Article type
Communication
Submitted
24 Mar 2014
Accepted
03 Jun 2014
First published
03 Jun 2014

Chem. Commun., 2014,50, 7848-7851

Author version available

Acid-free regioselective aminocarbonylation of alkenes

H. Liu, N. Yan and P. J. Dyson, Chem. Commun., 2014, 50, 7848 DOI: 10.1039/C4CC02167C

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