Issue 78, 2014

Guest-induced symmetry lowering of an ionic clathrate material for carbon capture

Abstract

We report a new lattice structure of the ionic clathrate hydrate of tetra-n-butylammonium bromide induced by guest CO2 molecules, which is found to provide high CO2 storage capacity. The structure was characterized by a set of methods, including single crystal X-ray diffraction, NMR, and MD simulations.

Graphical abstract: Guest-induced symmetry lowering of an ionic clathrate material for carbon capture

Supplementary files

Article information

Article type
Communication
Submitted
21 Mar 2014
Accepted
29 May 2014
First published
29 May 2014
This article is Open Access
Creative Commons BY license

Chem. Commun., 2014,50, 11476-11479

Guest-induced symmetry lowering of an ionic clathrate material for carbon capture

S. Muromachi, K. A. Udachin, K. Shin, S. Alavi, I. L. Moudrakovski, R. Ohmura and J. A. Ripmeester, Chem. Commun., 2014, 50, 11476 DOI: 10.1039/C4CC02111H

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements