Issue 50, 2014
From the journal:

Chemical Communications

Solid-state polymerization in a polyrotaxane coordination polymer via a [2+2] cycloaddition reaction†

In-Hyeok Park,a   Raghavender Medishetty,b   Shim Sung Lee*a  and  Jagadese J. Vittal*ab  

* Corresponding authors

a Department of Chemistry and Research Institute of Natural Science, Gyeongsang National University, Jinju 660-701, South Korea
E-mail: sslee@gnu.ac.kr
Fax: +82 55-753-7614
Tel: +82 55-772-1483

b Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543
E-mail: chmjjv@nus.edu.sg
Fax: +65 6779 1691
Tel: +65 6516 2975

Abstract

Alternate bpeb ligands in the polyrotaxane 2D coordination polymer [Cd(bpeb)(sdb)]·DMA (1) selectively undergo polymerization via a [2+2] cycloaddition reaction to form a polyrotaxane based 3D structure [Cd(bpeb)0.5(poly-bppcb)0.5(sdb)]·DMA (2) in a single-crystal-to-single-crystal manner.

Graphical abstract: Solid-state polymerization in a polyrotaxane coordination polymer via a [2+2] cycloaddition reaction

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C4CC02080D
Article type
Communication
Submitted
20 Mar 2014
Accepted
01 May 2014
First published
14 May 2014

Chem. Commun., 2014,50, 6585-6588

Permissions

Request permissions

Solid-state polymerization in a polyrotaxane coordination polymer via a [2+2] cycloaddition reaction

I. Park, R. Medishetty, S. S. Lee and J. J. Vittal, Chem. Commun., 2014, 50, 6585 DOI: 10.1039/C4CC02080D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements